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N = 1 ℓ = 0 m ℓ = 0 m s = ½ Notice the same n, ℓ, and m ℓ values, but m s has shifted from positive ½ to negative ½ This was the problem Pauli saw in 1925 Three quantum numbers was insufficient to UNIQUELY identify each electron, but a fourth one (the one called m s) did the trick. KOREAN J FOOD COOKERY SCI Vol 26, No 3, pp 238 æí245 (10) 238 ) Z ¥ í ¹ > *½ ' pYaV(é ¹ } Ñ Ú ï&³ áT , !. ǵ¡b 2 N>& e>8 Ç6ë> >8 Ç ì îª åº >* 2e)z @ %& ö @ O C >*)s)z @ %& ö @, 8 >' â U _C8\* , W 8 _ 9 ) Ý \ ǵ ¡b 2 N b 3Q &gM >, q A b Ç6ë\ CP b Ç ì îª åº>* r FC b Ç6ë\ N P b Ç ì îª åº>* s AC b Ç6ë\ FC b Ç ì îª åº b) s Oc%& ö@ OC>* t NP b Ç6ë\ FC b Ç ì îª åº>* u FC b Ç6ë.

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